On the way up, there are two forces on the block that are parallel to each other causing the deceleration - the component of weight parallel to the plane and the force of friction on the block. Since the forces are parallel to each other, both pointing down the plane, they add, causing a larger magnitude force and a larger acceleration. On the way down, those same two forces are opposite of each other, because the force of friction is now directed up the plane. With these two forces being opposite of each other, their net force is smaller, so the acceleration is smaller.