for a fixed amount of an ideal gas, the pressure times the volume, divided by the Kelvin temperature equals a constant; reduces to Boyle's law if temperature is constant and to Charles's law if pressure is constant
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zeroth law of thermodynamics
Front
two systems, each in thermal equilibrium with a third, are in thermal equilibrium with each other
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Carnot cycle
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consists of two reversible isothermal and two reversible adiabatic processess
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Kelvin
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temperature scale that uses absolute zero as its reference zero
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isothermal
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constant temperature
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isochoric
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constant volume
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heat of fusion
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the amount of heat required to change 1 kg of a substance from a solid state to a liquid state at its melting point
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ideal gas law
Front
for an ideal gas, the pressure times the volume is equal to the number of moles, times the constant, R, and the Kelvin temperature; predicts the behavior of gases remarkably well unless under high-pressure or low-temperature conditions
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heat
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energy transferred between two objects in contact with one another and always flows from the hotter object to the cooler object
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conduction
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the process by which kinetic energy is transferred when particles collide
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second law of thermodynamics
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states that natural processes go in a direction that maintains or increases the total entropy of the universe, heat can only flow from a warmer body to cooler body
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absolute zero
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the lowest temperature that is theoretically possible, at which the motion of particles would be minimal, 0 K, -273.15°C or -459.67°F
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adiabatic
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a process in which no heat enters or leaves the system
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specific heat
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the amount of energy that must be added to a material to raise the temperature of a unit mass by one temperature unit
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heat engine
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a device that continuously converts thermal energy to mechanical energy; requires a high-temperature thermal energy source, a low-temperature receptacle (a sink), and a way to convert the thermal energy into work
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Fahrenheit
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temperature scale that has a steam point of 212 degrees
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coefficient of linear expansion
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a change in length divided by the original length and the change in temperature
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isobaric
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constant pressure
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first law of thermodynamics
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states that the change in thermal energy of an object is equal to the heat that is added to the object plus the work done on the object
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thermal expansion
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a property of all forms of matter that causes the matter to expand, becoming less dense, when heated
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temperature
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the measure of the average kinetic energy of the molecules
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internal energy
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sum of kinetic and potential energy associated with the atoms composing a system
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entropy
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a measure of the disorder in a system
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Celsius
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temperature scale that divides the interval between the ice point and the steam point into 100 intervals and takes the ice point as zero
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thermal equilibrium
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the state in which the rate of energy flow between two objects is equal and the objects are at the same temperature
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convection
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a type of thermal energy transfer that occurs from the motion of fluid in liquid or gas that is caused by differences in temperature
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radiation
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the thermal transfer of energy by electromagnetic waves through the vacuum of space
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heat of vaporization
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the amount of heat required to change 1 kg of a substance from a liquid state to a gaseous state at its boiling point