AP Chemistry Semester 1 Review

AP Chemistry Semester 1 Review

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Section 1

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Mass Number

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Cards (142)

Section 1

(50 cards)

Mass Number

Front

the sum of the number of neutrons and protons in an atomic nucleus

Back

Mixtures

Front

homogeneous or heterogeneous that can separate into components based on physical properties

Back

Ion

Front

a particle that is electrically charged (positive or negative) because it has gained or lost electrons. (protons not equal to electrons)

Back

Carbonate

Front

CO3 (2−)

Back

Electron

Front

negatively charged particle in the outer space of the atom that has a mass of 5.486x10^-4. (Its mass is so small that most ignore it)

Back

Density

Front

varies with temperature and is an identifying property

Back

Elements

Front

Atoms or molecules bound together (on periodic table)

Back

Nitrite

Front

NO2 (−)

Back

Polyatomic Ions

Front

tightly bound groups of atoms that behave as a unit and carry a charge

Back

Cation

Front

a positively charged ion

Back

Permanganate

Front

MnO4 (−)

Back

Fahrenheit to Celsius

Front

C = (F - 32)/1.8

Back

Chlorate

Front

ClO3 (−)

Back

Hypochlorite

Front

CIO (−)

Back

Celsius to Fahrenheit

Front

F = 1.8 (C) + 32

Back

Atomic Number

Front

The number of protons and electrons in a stable atom.

Back

Iodate

Front

IO3 (−)

Back

Ionic Compound

Front

composed of positive and negative ions that are combined so that the numbers of positive and negative charges are equal. (a metal and a non-metal)

Back

Density Equation

Front

Density = (mass)/(volume)

Back

Thiocyanate

Front

SCN (−)

Back

Cyanide

Front

CN (−)

Back

Cathode Ray Experiment

Front

This was JJ Thomson's experiment that led to the discovery of the electron and the development of the plum pudding model of the atom. The rays repelled by the negative electric field and the magnetic force causes the negative particle to move in circular motion.

Back

Molecular Compound

Front

a compound made up of two non metals; sharing electrons

Back

Compounds

Front

Pure substance that includes more than one element

Back

Dichromate

Front

Cr2O7 (2−)

Back

Chlorite

Front

ClO2 (−)

Back

Heterogeneous Mixtures

Front

mixture in which the composition is not uniform throughout

Back

Hydrogen Sulfate (bisulfate)

Front

HSO4 (−)

Back

Naming Ionic Compounds

Front

Metals are written 1st, non-metals last. Change the ending of non-metal to "ide" unless it is a polyatomic ion. Ignore the subscripts.

Back

Homogeneous Mixtures

Front

a mixture in which substances are evenly distributed throughout the mixture

Back

Nitrate

Front

NO3 (−)

Back

Neutron

Front

no charged particle in the nucleus that has a mass of about 1 amu

Back

Acetate

Front

CH3COO (−)

Back

Hydride

Front

H (−)

Back

Naming Molecular Compounds

Front

1. The name of the element to the left is named first 3. The name of the second element is given an -ide, unless polyatomic ion. 4. Greek prefixes should be used before both elements (Ex: dihydrogen triphosphide) 5. no "mono" for first element (Ex: carbon dioxide)

Back

Perchlorate

Front

CIO4 (−)

Back

Celsius to Kelvin

Front

K = C + 273.15

Back

Bromate

Front

BrO3 (−)

Back

Oil Drop Experiment

Front

Robert Millikan, suspended oil drops between charged plates, shot x-rays that put an electron on them, determined the smallest increment of charge difference needed to suspend the drops, and determined the charge on one electron

Back

Isotope

Front

an atom that has the same number of protons (or the same atomic number) as other atoms of the same element do but that has a different number of neutrons

Back

Anion

Front

a negatively charged ion

Back

Gold Foil Experiment

Front

Conducted by Ernest Rutherford in which alpha particles that were shot at gold foil were deflected when they hit the positive center of gold atoms. The nucleus was discovered as a result of this experiment.

Back

Chromate

Front

CrO4 (2−)

Back

Dihydrogen Phosphate

Front

H2PO4 (−)

Back

Hydroxide

Front

OH (−)

Back

Molecule

Front

two or more atoms held together by covalent bonds

Back

Greek Prefixes for Molecular Compounds

Front

mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca

Back

Proton

Front

positively charged particle in the nucleus that has a mass of about 1 amu.

Back

Hydrogen Carbonate (bicarbonate)

Front

HCO3 (−)

Back

Formate

Front

HCOO (−)

Back

Section 2

(50 cards)

Oxalate

Front

C2O4 (2−)

Back

Borate

Front

BO3 (3−)

Back

Oxidation Reaction

Front

a chemical reaction in which a reactant loses one or more electrons such that the reactant becomes more positive in charge

Back

Ammonium

Front

NH4 (+)

Back

Decomposition Reactions

Front

complex substances are broken up into simpler substances (AB -> A+B)

Back

Exergonic

Front

chemical reaction that releases some form of energy, such as heat.

Back

Net Ionic Equation

Front

an equation that includes only those compounds and ions that undergo a chemical change in a reaction in an aqueous solution (aka: removing ions that are on both sides of the equation)

Back

Synthesis (Combination) Reactions

Front

two or more substances combine to form a more complex substance (A+B -> AB)

Back

Solubility Rules

Front

1. Soluble Compounds - Anions if a compound contains one of the following Anions, they will be soluble: •Acetates •Chlorates •Perchlorates •Nitrates •Nitrites •Permanganates

Back

Work

Front

energy used to cause an object that has mass to move

Back

Enthalpy

Front

(thermodynamics) a thermodynamic quantity equal to the internal energy of a system plus the product of its volume and pressure

Back

Pauli Exclusion Principle

Front

no two electrons or protons or neutrons in a given system can be in states characterized by the same set of quantum numbers

Back

Neutralization Reaction

Front

a chemical reaction in which an acid and a base interact with the formation of a salt and water (EX: HCl + NaOH --> NaCl (aka: the salt) + H2O (aka: water))

Back

Naming Oxyacids

Front

former suffix "ate;" root + ic. former suffix "ite;" root + ous. "i ATE ICky food at the whITE hOUSe." (EX: Perchlorate -> HCIO4: perchloric acid)

Back

Heat

Front

Energy used to cause the temperature of an object to rise

Back

Precipitation Reaction

Front

a reaction in which an insoluble substance forms and separates from the solution by combining two soluble substances.

Back

Reduction Reaction

Front

a reactant gains one or more electrons, thus becoming more negative in charge

Back

Sulfite

Front

SO3 (2−)

Back

Solubility Rules (cont.)

Front

2. Soluble Compounds - Cations if a compound contains one of the following Cations, it will be soluble. •NH4 (positive charge of 1) and Almost all of the Group 1A alkali Cations

Back

Relationship of Energy to Work and Heat

Front

Energy = heat + work

Back

endothermic

Front

describes a process in which heat is absorbed from the surroundings

Back

Mercury I

Front

Hg2 (2+)

Back

Naming Binary Acids

Front

1) Take root of second element, 1A) add "-hydro" prefix to the anion 1B) add "-ic" suffix" 2) Add acid as second word (EX: hydrochloric acid)

Back

Potential Energy

Front

energy stored due to an object's position or arrangement

Back

Thiosulfate

Front

S2O3 (2−)

Back

Atomic Radius Trend

Front

Across a period: decreases. Down a group: increases

Back

Gas Forming Reactions

Front

occur through the formation of a gas and water because both products remove ions from the solution; include carbonate, sulfite, Sulfide (all are polyatomic) and NH4OH (but last one is not as common).

Back

Endergonic

Front

A chemical reaction that requires the input of energy in order to proceed.

Back

Sulfide

Front

S (2−)

Back

Arsenate

Front

AsO4 (3−)

Back

System

Front

molecules chemist want to study

Back

Solubility Rules (cont..)

Front

3. Soluble Compounds with EXCEPTIONS If a compound contains one of the following Anions, they will be soluble: ------Chlorides, Bromides, Iodides {Except those compounds of Ag (+1), Hg2 (+2), and Pb (+2)} ------Sulfates {Except those compounds of Sr (2+), Ba (2+), Hg2 (2+), and Pb (2+)

Back

Complete Ionic Equation

Front

a reaction equation that shows all soluble compounds in their ionic forms (aka: it shows NaCl as Na+ and Cl−)

Back

Combustion Reaction

Front

a substance (most often a hydrocarbon) combines with oxygen, producing carbon dioxide and water

Back

Solubility Rules (cont...)

Front

4. Insoluble Compounds with EXCEPTIONS If a compound contains one of the following Anions, they will be insoluble: ------Carbonates, Phosphates, Sulfites {Except those compounds of NH4 (+), and alkali metals cations} ------Hydroxides, Sulfides {Except those compounds of NH4 (1+), alkali metals, and Ca (2+), Sr (2+), and Ba (2+)}

Back

Surroundings

Front

everything other than the system

Back

Molecular Equations

Front

A reaction equation which shows all soluble compunds in their ionic forms, a chemical equation written using the complete formulas of reactants and products (aka the original equation)

Back

Exothermic

Front

describes a process in which heat is released to the surroundings

Back

Sulfate

Front

SO4 (2−)

Back

Hund's Rule

Front

orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron, and all electrons in singly occupied orbitals must have the same spin

Back

Kinetic Energy

Front

the energy an object has due to its motion

Back

Energy

Front

the ability to do Work or transfer heat

Back

Phosphate

Front

PO4 (3−)

Back

Peroxide

Front

O2 (2−)

Back

Phosphide

Front

P (3−)

Back

hydrogen phosphate

Front

HPO4 (2−)

Back

Nitride

Front

N (3−)

Back

Oxide

Front

O (2−)

Back

Exceptions to Hund's Rule

Front

Chromium ([Ar] 4s1 3d5) Copper ([Ar] 4s1 3d10) molybdenum ([Kr] 5s1 4d5) Silver ([Kr] 5s1 4d10) Gold ([Xe] 6s1 4f14 5d10)

Back

Arsenite

Front

AsO3 (3−)

Back

Section 3

(42 cards)

Octrahedral

Front

6 electron domains; no lone pairs. Bond angles: 90 degrees (hybridizations: sp3d2)

Back

Bent (aka: trigonal planar - bent)

Front

3 electron domains; 1 lone pair. Bond angles: less than 120 degrees (hybridizations: sp3)

Back

Seesaw

Front

5 electron domains; 1 lone pair. Bond angles: 90 and 120 degrees (hybridizations: sp3d)

Back

Pi bonds

Front

Side to side overlap of orbitals; this is in double and triple bonds. Double bonds have one sigma and one pi bond. Triple bonds have one sigma and two pi bonds.

Back

Phase Diagrams

Front

a graph of pressure versus temperature that shows in which phase a substance exists under different conditions of temperature and pressure

Back

alpha particle

Front

a positively charged particle that is the nucleus of the helium atom; affects mass number by 4 and atomic number by 2.

Back

Ionization Energy Trend

Front

decreases from top to bottom in a group; increases from left to right in a period EXCEPTIONS: 2A-3A; 5A-6A

Back

gamma particle

Front

no charge; , High energy that only lead and concrete can stop

Back

Conditions of STP

Front

273 K or 0 C, 1 atm

Back

Tetrahedral

Front

4 electron domains; no lone pairs. Bond angles: 109.5 degrees (hybridizations: sp3)

Back

Polarizability

Front

the ease with which the electron distribution in the atom or molecule can be distorted

Back

T-shaped

Front

5 electron domains; 2 lone pairs. Bond angles: 90 degrees (hybridizations: sp3d)

Back

beta particle

Front

affects atomic number by increasing by 1; this emission is helping when higher than belt of stability

Back

Heat capacity

Front

The amount of heat required to raise the temperature of a specified amount of a substance by 1°C or 1 K.

Back

Square Pyramidal

Front

6 electron domains; 1 lone pair. Bond angles: 90 degrees (hybridizations: sp3d2)

Back

Square Planar

Front

6 electron domains; 2 lone pairs. Bond angles: 90 degrees (hybridizations: sp3d2)

Back

Isoelectronic series

Front

a group of ions all containing the same number of electrons Ex: Li(+), Be(2+), N(3-), O(2-), F(-))

Back

VSEPR theory

Front

a theory that predicts some molecular shapes based on the idea that pairs of valence electrons surrounding an atom repel each other.

Back

Ionization Energy

Front

the amount of energy required to remove an electron from an atom

Back

Trigonal pyramidal

Front

4 electron domains; 1 lone pair. Bond angles: less than 109.5 degrees (hybridizations: sp3)

Back

Sigma bonds

Front

single covalent bonds; there is always ONE in any bond (either it be single, double, or triple)

Back

Lattice energy

Front

the energy required to separate one mole of the ions of an ionic compound; q1q2/d

Back

Electron Affinity

Front

the energy needed to remove an electron from a negative ion to form a neutral atom or molecule

Back

Hydrogen Bonding

Front

The intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom (Fluorine, Oxygen, and Nitogen) is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.

Back

Intermolecular Interactions affecting Boiling/ Melting Points

Front

The higher the intermolecular force, the higher the boiling and melting points

Back

Linear (aka: trigonal bipyramidal - linear)

Front

5 electron domains; 3 lone pairs. Bond angles: 180 degrees (hybridizations: sp3d)

Back

Bent (aka: tetrahedral - bent)

Front

4 electrol domains; 2 lone pairs. Bond angles: less than 109.5 degrees (hybridizations: sp3)

Back

Electronegativity Trend

Front

decreases from top to bottom in a group; increases from left to right in a period

Back

Trigonal bipyramidal

Front

5 electron domains; no lone pairs. Bond angles: 90 and 120 degrees (hybridizations: sp3d)

Back

Trigonal planar

Front

3 electron domains; no lone pairs. Bond Angles: 120 degrees (hybridizations: sp2)

Back

Kinetic Molecular Theory

Front

the theory that all matter is composed of particles (atoms and molecules) moving constantly in random directions

Back

Intermolecular Interactions affecting Bond Strength

Front

The higher the intermolecular force, the stronger the bond.

Back

Electron Affinity Trend

Front

increases going across because atoms are stable enough to hold onto their own electrons and take others from other atoms. decreases going down because size of orbitals increase making the atoms unstable EXCEPTIONS: 1A-2A; 4A-5A

Back

Conditions of real gases

Front

low temperature, high pressure

Back

Heating Curves

Front

graphical representation of phase changes (HEATING curves: start in solid phase and COOLING curves: start in gas phase)

Back

Dipole-dipole

Front

created by equal but opposite charges that are separated by a short distance

Back

Condition of ideal gases

Front

high temperature, low pressure

Back

Electronegativity

Front

(chemistry) the tendency of an atom or radical to attract electrons in the formation of an ionic bond

Back

Molar Volume of a gas at STP

Front

22.4 L

Back

London-disperson forces

Front

A temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Back

Metallic Trend

Front

increases down a group, decreases across a period

Back

Linear

Front

2 electron domains, no lone pairs. Bond angles: 180 degrees (hybridizations: sp)

Back