An atom is the smallest fundamental particle of matter that contains its own properties.
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Modern Atom
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the identity of atoms are determined by the number of protons ( atomic # ( Z #) )
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Dalton's Atomic Theory (Hard Sphere Theory)
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the modern description of matter
States:
* all matter is composed of hard indestructible spheres called atoms
*atom of the same elements are the same while atoms of different elements differ in a fundamental way.
* chem. compounds are produced when atoms of diff. atoms combine in specific mass ratios unique to the compound
* chem. reactions occur when atoms are reorganized and rebound with no changes in the atoms themselves
- est. first table of atomic masses (most were wrong)
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Elementary Treatise on Chemistry
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summary of all known chemical knowledge at that point in time (1789)
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Alchemists tried...
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to make gold through chemistry
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Polyatomic Ions
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Nuclear Model
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Atoms are composed of mainly empty space with a small positively charged center called a nucleus, surrounded by negatively charged electrons
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Imperical formula
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chemical formula that gives the simplest whole number ratio of atoms in a compound * lowest terms
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monoatomic ions
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have an -ide suffix added to nonmetal roots
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Molecular formula
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chemical formula that gives the exact number of atoms present in each compound
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Law of Multiple Proportions
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if multiple compounds can be produced by a set of elements, the ratio of elements varies by whole numbers
** This occurs because the number of atoms, which were not yet discovered, varied by whole numbers
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Isotopic Name
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* write element name
* place hyphen/dash
* write mass #
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Joseph Gay-Lussac
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1. studied volume changes associated with gaseous chemical reactions under constant conditions
* used law of def. prop. & law of mult. prop.
2. observed that gases react in specific ratio
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polyatomic ions...
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keep their original name
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Model
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Simplified presentation of something
* space filling model
* ball and stick
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+/-
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gaining -
losing +
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atomic mass
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relative mass of an element measured in AMU's
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Robert Boyle
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1. first true quantitative experimenter
2. est. the idea of elements
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Anions & Names
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H- Hydride
F- Fluoride
Cl - Chloride
Br - Bromide
I - Iodide
O 2- Oxide
S 2- Sulfide
N 3- Nitride
P 3- Phosphide
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AMU
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atomic mass units
(1/12 mass of a carbon-12 isotope)
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Demokritus & Leucippos
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Matter is composed of tiny indivisible objects called "Atomos".
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Atomic Mass
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weighted average mass of all isotopes in an element
* Fractional Abundance (mass #) + FA + FA...
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Amedeo Avagadro
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** Avagadro's Hypothesis
1. used Gay -Lussac's data and Law of Def. Prop. to predict that the volume of a gas must be directly related to the number of particles in said gas
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Joseph Proust
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* father of analytical chemistry
1. studied the composition of elements in compounds
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isotope
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atoms of the same element with differing mass numbers
* same number of protons but a different number of neutrons
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covalent compound
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(molecular)
atoms are held together by electrons being "shared" within overlapped outer shells
* formed between non-metals
* identified by 1st element being a non-metal
- naming:
> first element keeps name
>second elements root gets -ide ending
> use Greek prefixes to indicate the number of atoms present
* Never place mono on the first element *
*stimulated by Proust's work
1. Law of Multiple Proportions
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Ernest Rutherford
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1. conducted Gold Foil Experiment
2. discovered
* atoms are mainly empty space
* they have a massive center
* they are positively charged
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Antoine Lavoisier
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* complete stud
1. studied chemical reactions
2. took careful measurements
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anode
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positive charge, attracts anions
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Element is..
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groups of atoms with the exact same chemical properties
* atoms of the same type
* contains the same number of protons and electrons, but may differ in the number of neutrons
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JJ Thomson
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1. idea of an atom made sense from previous work of other scientists
2. studied cathode rays
3. observed deflection of rays by electric & magnetic fields
** m/e = -1.766 x 10^8 c/g
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Law of Definite Proportions
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the mass ratio of elements in a compound must always be constant (conversion factor)
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Common Type 2 Cations
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Fe 3+ / Fe 2+
Cu 2+ / Cu +
Co 3+ / Co 2+
Sn 4+ / Sn 2+
Pb 4+ / Pb 2+
Hg 2+ / Hg2 2+ (Mercury I)
Ag +
Zn 2+
Cd 2+
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atoms are...
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electrically charged due to the gain or loss of electrons
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polyatomic cations...
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keep their metal name
* divalent cations must be specifically named (ous/ic)
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ionic compound
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compound held together by electrostatic attractions getting between oppositely charged ions
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Mass Number
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sum of all nucleons ( protons & neutrons)
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compounds are...
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chemical combinations of two or more elements
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Isotopic Symbol
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* write symbol of element
* place atomic # in lower Left side
* top left corner is mass number
* number of neutrons = protons - electrons
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1 mole =
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22.4 L @ STP /// 6.02 x 10^23 /// 1 AMU
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ion
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variation of an element/atom
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Cations & Names
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H+ Hydrogen
Li + Lithium
Na + Sodium
K + Potassium
Cs + Cesium
Be 2+ Beryllium
Mg 2+ Magnesium
Ca 2+ Calcium
Ba 2+ Barium
Al 3+ Aluminum
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Robert Millikan
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1. conducted oil drop experiment
2. determined mass and change of electron
** mass = 9.109 x 10^3 kg
** change = 1.6 x 10^-19 coulombs (-1 fundamental charge)
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Law of Conservation of Mass
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the amount of mass in any chemical process must remain constant
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cathode
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negative charge, attracts cations
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electrons...
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determine all chemical properties
* found outside nuceus
* ignorable mass
*-1 charge